homolytic dissociative adsorption

https://doi.org/10.1351/goldbook.H02852
Relates in the usual sense to the formal nature of the cleavage of a single bond. If the electron pair in the bond of the @A00166@ A :B is divided in the course of its @D01803@, the @A00155@ is homolytic dissociative adsorption.
Source:
PAC, 1976, 46, 71. (Manual of Symbols and Terminology for Physicochemical Quantities and Units - Appendix II. Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis) on page 76 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014