mixing control

https://doi.org/10.1351/goldbook.M03946
The experimental limitation of the @R05156@ in solution by the rate of mixing of solutions of the two reactants. It can occur even when the reaction @O04322@ is several powers of 10 less than that for an @E02089@ rate. Analogous (and even more important) effects of the limitation of reaction rates by the speed of mixing are encountered in heterogeneous (solid/liquid, solid/gas, liquid/gas) systems.
See also:
microscopic diffusion control
,
stopped flow
Sources:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1141 [Terms] [Paper]
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 174 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014