multi-centre bond
Representation of some @[email protected] solely by localized two-electron two-centre @[email protected] appears to be unsatisfactory. Instead, multi-centre bonds have to be considered in which electron pairs occupy orbitals encompassing three or more atomic centres. Examples include the three-centre bonds in diborane, the delocalized π-bonding of benzene and @[email protected]
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1144 [Terms] [Paper]