For a reactant molecule RY, the polar effect of the group R comprises all the processes whereby a substituent may modify the electrostatic forces operating at the reaction centre Y, relative to the standard \(\text{R}^{\text{o}}\text{Y}\). These forces may be governed by charge separations arising from differences in the @[email protected] of atoms (leading to the presence of dipoles), the presence of unipoles, or electron @[email protected] It is synonymous with @[email protected] or 'electrical effect' of a substituent as distinguished from other substituent effects, e.g. @[email protected] Sometimes, however, the term 'polar effect' is taken to refer to the influence, other than steric, that non-conjugated substituents exert on reaction rates, i.e. effects connected with electron @[email protected] between a substituent and the molecular framework to which it is attached are excluded. Polar effect is then not synonymous with electronic effect
See also:
field effect
inductive effect
mesomeric effect
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1150 [Terms] [Paper]