polytopal rearrangement

https://doi.org/10.1351/goldbook.P04755
Stereoisomerization interconverting different or equivalent spatial arrangements of @[email protected] about a @[email protected] or of a @[email protected] of atoms, where the ligand or @[email protected] defines the vertices of a polyhedron. For example @[email protected] of @[email protected], @[email protected] of PF5, rearrangements of polyhedral @[email protected]
Source:
PAC, 1996, 68, 2193. (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2213 [Terms] [Paper]