radiative lifetime, \(\tau_{0}\)

Also contains definition of: natural lifetime
@[email protected] of an excited molecular entity in the absence of radiationless transitions. The reciprocal of the first-order @[email protected] for the radiative step, or the reciprocal of the sum of these rate constants if there is more than one such step. The equivalent term, natural lifetime, is discouraged.
  1. Approximate expressions exist relating \(\tau_{0}\) to the @[email protected] of the emitting transition.
  2. The subscript \(0\) is used in this definition, whereas the superscript \(0\) is used to indicate a non-quenched @[email protected] in the Stern-Volmer kinetic relationships.
PAC, 2007, 79, 293. (Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)) on page 411 [Terms] [Paper]