through-bond electron transfer

https://doi.org/10.1351/goldbook.T06367
@[email protected] @[email protected] for which the relevant electronic interaction between the donor and acceptor sites is mediated by through-bond interaction, i.e. via the covalent bonds interconnecting these sites, as opposed to through-space interaction.
See also:
through-space electron transfer
Source:
PAC, 1996, 68, 2223. (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2280 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014