variational transition state theory

https://doi.org/10.1351/goldbook.V06603
This expression is applied to modifications of conventional @[email protected] in which the position of the @[email protected] in the potential-energy surface is varied. The rate is calculated with the surface at various positions, and the lowest rate calculated is taken to be closest to the truth.
Source:
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 190 [Terms] [Paper]