work of cohesion per unit area
Of a single pure liquid or solid phase α, \(w_{\text{C}}^{\unicode[Times]{x3B1} }\) is the work done on the system when a column α of unit area is split, reversibly, normal to the axis of the column to form two new surfaces each of unit area in contact with the equilibrium gas phase. \[w_{\text{C}}^{\unicode[Times]{x3B1} }=2\ \gamma ^{\unicode[Times]{x3B1} }\] where \(\gamma ^{\unicode[Times]{x3B1} }\) is the @[email protected] between phase and its equilibrium vapour or a dilute gas phase.
PAC, 1972, 31, 577. (Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry) on page 597 [Terms] [Paper]