canonical variational transition-state theory (CVTST)
A development of @T06470@ in which the position of the @D01823@ is varied so as to minimize the @O04322@ at a given temperature.
microcanonical variational transition-state theory
Source: PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 155 [Terms] [Paper]
Citation: 'canonical variational transition-state theory ' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.C00790 RISBibTexEndNote