surface excess enthalpy

https://doi.org/10.1351/goldbook.S06174
Defined by: \[H^{\sigma }=U^{\sigma }- \gamma \ A_{\text{s}}\] where \(U^{\sigma }\) is the @[email protected], \(\gamma \) is the @[email protected], and \(A_{\text{s}}\) is the area relative to a @[email protected]
Source:
PAC, 1972, 31, 577. (Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry) on page 599 [Terms] [Paper]
Cite as: IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook.
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Last revised: February 24, 2014