surface excess entropy

https://doi.org/10.1351/goldbook.S06175
Defined by: $S^{\unicode[Times]{x3C3}} = S - S^{\unicode[Times]{x3B1} }- S^{\unicode[Times]{x3B2} }=S- V^{\unicode[Times]{x3B1} }\ \frac{S_{\text{m}}^{\unicode[Times]{x3B1} }}{V_{\text{m}}^{\unicode[Times]{x3B1} }}- V^{\unicode[Times]{x3B2} }\ \frac{S_{\text{m}}^{\unicode[Times]{x3B2} }}{V_{\text{m}}^{\unicode[Times]{x3B2} }}$ ($$\frac{S_{\text{m}}^{\unicode[Times]{x3B1} }}{V_{\text{m}}^{\unicode[Times]{x3B1} }}$$) and ($$\frac{S_{\text{m}}^{\unicode[Times]{x3B2} }}{V_{\text{m}}^{\unicode[Times]{x3B2} }}$$) are the @E02149@ densities in the two bulk phases, where $$S_{\text{m}}^{\unicode[Times]{x3B1} }$$ and $$S_{\text{m}}^{\unicode[Times]{x3B2} }$$ are the mean molar entropies and $$V_{\text{m}}^{\unicode[Times]{x3B1} }$$ and $$V_{\text{m}}^{\unicode[Times]{x3B2} }$$ are the mean molar volumes of the two phases.
Source:
PAC, 1972, 31, 577. (Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry) on page 599 [Terms] [Paper]